Author: JAGS

2D-heterostructure transfer system

The 2D-heterostructure transfer system allows the transfer of exfoliated layered materials onto surfaces of various substrates and consists of fully motorized micro-manipulators with a total of 8 degrees of freedom and operate under a high resolution microscope with variable substrate temperature (from room temperature up to around 150ºC). The system includes:

  • Sample unit: Three degree of motion (Translation (x,y), Rotation (360º))
  • Transfer unit: Five degree of motion (Translation (x,y,z), Goniometer (x,y))
  • Microscope (DP23): High resolution microscope Long working distance objectives (5x, 10x, 20x, 50x)
  • Sample holder: equipped with temperature control (range RT-120oC) and vacuum hole for affixing sample. Goniometer control allow alignment of glass slide

Magneto-optic spectroscopy lab

The magneto-optic spectroscopy setup works from UV to near IR (wavelength range ~ 350 – 1000 nm). We carry out measurements of Kerr/Faraday rotation and ellipticity from 8 K up to 320 K, and with magnetic fields up to ~ 1.5 – 2 Tesla. The setup can work on different geometrical Kerr configurations (where we measure the light reflected from samples), including polar, longitudinal and transverse Kerr.

Gervasi Herranz participate at the APS March Meeting

Gervasi Herranz delivers on 8th of March a talk at the APS March Meeting (Las Vegas, Nevada, USA)in focus session : The talk is entitled “(N38) Spin-orbit mixed states in an electromagnetic field” in FOCUS SESSION “Light Induced Structural Control of Electronic Phases III”.

2022

Electrical manipulation and detection of magnetization in magnetic insulators
Can Onur Avci
University of Bialystok, Physics Faculty Seminars, 8 Nov. 2022 (Virtual)

Trends and opportunities in metallic and insulating spintronics
Can Onur Avci
Samsung Advanced Institute of Technology, Jun. 15, 2022 (Virtual)

Trends and opportunities in metallic and insulating spintronics
Can Onur Avci
ICN2 – Severo Ochoa Workshop – Beyond CMOS: Alternative Computing Paradigms, Apr. 22, 2022, Barcelona, Spain

Insulating Spintronics using rare-earth ferrimagnetic garnets
Can Onur Avci
Physics Deparment of the Centro Atómico
Bariloche, Argentina 18 Apr. 2023 (virtual)

New artificial structures for topological spintronics
Jak Chakhalian
Mon, 14 March 2023)  ICMAB

New Heterostructured Materials for Electronics and Spintronics
Chang-Beom Eom
April 20th 2023  ICMAB

2023

INVITED TALKS

Electron-phonon vs electron-electron correlations in early-transition metal conducting oxides
Josep Fontcuberta
The 13th International Conference on Advanced Materials and Devices ICAMD 2023
Dec. 4-8, 2023, Jeju, Korea

Growth, optimization, and electrical manipulation of rare-earth iron garnets for efficient spintronics
Can Onur Avci
JEMS2023 Joint European Magnetic Symposia
Aug. 28- Sep 02, 2023, Madrid, Spain.

Growth, optimization, and electrical manipulation of rare-earth iron garnets for efficient spintronics
Can Onur Avci
SPIE Spintronics-XVI
Aug. 20-24, 2023, San Diego, USA

Growth, optimization, and electrical manipulation of rare-earth iron garnets for spintronic applications
Can Onur Avci
IEEE International Magnetics Conference INTERMAG 2023
May. 15-19, 2023, Sendai, Japan

Rare-earth iron garnets with perpendicular magnetic anisotropy for efficient spintronics
Can Onur Avci
8th International Conference on Superconductivity and Magnetism (ICSM2023)
May 4-11 2023, Fethiye Turkey

REGULAR TALKS

Spin-orbit mixed states in an electromagnetic field
Gervasi Herranz
APS March Meeting
Las Vegas, Nevada, USA, 2023

Electron-phonon and spin-orbit coupling in early-transition metal conductive oxides
Josep Fontcuberta
APS March Meeting
Las Vegas, Nevada, USA, 2023

Wedge Wirebonder

We have a ultrasonic wedge bonder designed to interconnect micron-scale wire leads between samples holders and devices. The machine can bond aluminum or gold wires of ranging diameter (typically a few 10s of um).

Magneto-electric characterization

We have two electrical probe stations that allow us to measure longitudinal and transverse resistances in Hall bar devices using a lock-in technique. In the first station, DUTs are mounted on a motorized rotation stage and electrically connected using a wire bonder. The DUT can be rotated 360° in any given plane between the poles of an electromagnet producing fields up to 2.3 Teslas.

The second station uses the same measurement principles as the first one but the DUTs are contacted using microprobes and we are able to apply field along two axes simultaneously (in-plane 0.3 T and out-of-plane 0.05 T).  

Setups are complemented with a constant ac/dc current source, a pulse generator (1-100 ns, -/+50V), a high voltage source (<1.1 kV), an arbitrary waveform generator, and a high speed advanced oscilloscope. 

Magnetron Sputtering

We have a dual-chamber magnetron sputtering tool with dc and rf deposition capabilities. Chambers are dedicated to metal and oxide deposition, respectively, with a separate load lock chamber. We can deposit from two different targets simultaneously (co-deposition) in both chambers, and they can operate independently. Currently, the two chambers accommodate nine targets with a possibility of an upgrade up to seventeen. The oxide chamber has a gun for off-axis deposition, a unique feature to deposit stoichiometric films from multi-element targets. Reactive gases are also available (O2 and N2). The sample holder can rotate, be heated (up to 850°C), and apply a transverse magnetic field of 20 mT on the substrate during the deposition. Both chambers work at a base pressure in the low 10^8 Torr. 

L. FÀBREGA

ONGOING PHD THESES

Manel Mas (since october 2020)
Subject of PhD thesis: Electrothermal modeling and physics of the transition of Transition Edge Sensors (TES)

L. FÀBREGA

Title of the Project: Beyond Athena: Broadening TES application prospects
Reference:  PID2021-122955OB-C42
Principal Investigators: A.Camón, L.Fàbrega Funding Agency: AEI (MICINN)
Period: 01/10/2022-30/09/2025
Amount: 121 k€

Title of the Project: Phonon dynamics as ruling factor for detection of light dark matter with quantum sensors
Reference:  FYP11
Principal Investigators: L.Fàbrega, R.Rurali
Funding Agency: ICMAB throug AEI (Severo Ochoa Frontier Interdisciplinary Project)
Period: 01/5/2022-30/11/2023
Amount: 60 k€

Title of the Project: Phonon dynamics as ruling factor for detection of light dark matter with quantum sensors
Reference:  FYP11
Principal Investigators: L.Fàbrega, R.Rurali
Funding Agency: ICMAB through AEI (Severo Ochoa Frontier Interdisciplinary Project)
Period: 01/5/2022-30/11/2023
Amount: 60 k€

Title of the Project: Quantum sensing for Dark Matter (QS4DM)
Reference:  20219PT027
Principal Investigator: I.Vila Funding Agency:QTEP+ through NGEU
Period: 01/1/2021-18/11/2024
Amount: 862,73 k€ (total, 4 research institutes)

Title of the Project: “Integrated activities for the high energy astrophysics domain” (AHEAD2020) Reference grant agreement 871158
Principal Investigators: L.Piro
Funding Agency: EC, Call  INFRAIA-01-2018-2019
Period: 01/1/2020-1/12/2024
Amount: 10 M€ (total, 28 institutions of 17 countries)

2019

G. Herranz, CHAPTER 10: “Orbital Symmetry and Electronic Properties of Two-Dimensional Electron Systems in Oxide Heterointerfaces” in the book entitled: “Oxide Spintronics”
Edited by T. Banerjee, Pan Stanford Publishing, 2019,
ISBN 9814774995

2023

Insulating Spintronics using rare-earth ferrimagnetic garnets
Can Onur Avci
Physics Deparment of the Centro Atómico
Bariloche, Argentina 18 Apr. 2023 (virtual)

New artificial structures for topological spintronics
Jak Chakhalian
Mon, 14 March 2023)  ICMAB

New Heterostructured Materials for Electronics and Spintronics
Chang-Beom Eom
April 20th 2023  ICMAB

2022

Symposium – Topologically Protected Spin Textures: Physics and Applications

Can Onur Avci

International Conference on Quantum Materials and Technologies
ICQMT2022
Oct. 16-22, 2022
Bodrum, Turkey.

2023

Symposium – Advances in Current-Induced Magnetization Control

Can Onur Avci

International Conference on Magnetism and Superconductivity
ICSM2023
May 04-11, 2023
Fethiye, Turkey.

2023

ORBITAL CURRENTS SCHOOL 2023

Orbital currents in solids. The latest twist in a nutshell

Institute of Materials Science of Barcelona (ICMAB, CSIC), 30 NOVEMBER – 1 DECEMBER 2023

https://orbitalcurrents2023.icmab.es/

ARPES2023

Angle Resolved Photoemission Spectroscopy: From fundamentals to the heart of condensed matter

Institute of Materials Science of Barcelona (ICMAB, CSIC), 6–7 FEBRUARY 2023

https://arpes2023.icmab.es/

2023

Universitat Autònoma de Barcelona
Bachelor degree on Nanoscience and Nanotechnology
Lectures on “Advanced Nanomaterials”
Professor: Josep Fontcuberta

2022

Universitat Autònoma de Barcelona
Bachelor degree on Nanoscience and Nanotechnology
Lectures on “Advanced Nanomaterials”
Professor: Josep Fontcuberta

2021

Universitat Autònoma de Barcelona
Bachelor degree on Nanoscience and Nanotechnology
Lectures on “Advanced Nanomaterials”
Professor: Josep Fontcuberta

2020

Universitat Autònoma de Barcelona
Bachelor degree on Nanoscience and Nanotechnology
Lectures on “Advanced Nanomaterials”
Professor: Josep Fontcuberta

2019

Universitat Autònoma de Barcelona
Bachelor degree on Nanoscience and Nanotechnology
Lectures on “Advanced Nanomaterials”
Professor: Josep Fontcuberta

2018

Universitat Autònoma de Barcelona
Bachelor degree on Nanoscience and Nanotechnology
Lectures on “Advanced Nanomaterials”
Professor: Josep Fontcuberta

J. GAZQUEZ

ONGOING PhD Thesis (Gervasi Herranz):

  • Mario Villa Navas
    Supervised by J. Gazquez
    defense expected for 2026

BACHELOR THESES (since 2017):

  • Bernat Mundet Bolòs
    UAB Degree on Physics
    Supervisor: J. Gazquez
    October 2018

C.O. AVCI

Postdoctoral Associates

02/2022 – present: Silvia Damerio (Marie Sklodowska-Curie Fellow starting from 09/2023)
01/2023 – 04/2023: Martín Testa Anta (Juan de la Cierva Fellow – withdrawn)
03/2023 – present: Jesús Alejandro de Sousa

PhD Students
09/2021 – present: Stefano Fedel
03/2023 – present: Matteo Fettizio
03/2021 – 12/2022: Martín Testa Anta (discontinued due to the Juan de la Cierva fellowship award)

MSc/BSc Finishing Thesis

09/2022 – 01/2023: Júlia Mateu Comas – University of Barcelona / ICMAB-CSIC
11/2021 – 08/2022: Leo Salgado Chane-Pane – Autonomous University of Barcelona /ICMAB-CSIC
10/2021 – 06/2022: Teodor Parella [JAE Intro Fellow] – Autonomous University of Barcelona /ICMAB-CSIC

MSc-BSc Projects/Internships

09/2022-01/2023: Iker Barragán Martin – UB/ICMAB-CSIC
09/2022-02/2023: Loes Fransen, ICMAB-CSIC (visiting from TU Eindhoven)

GERVASI HERRANZ

ONGOING PhD Thesis (Gervasi Herranz):

  1. Jiahui Jia, Supervised by G. Herranz/M. Pruneda (CIN2), defense expected for 2023
  2. Alejandro Sánchez Miñarro, Supervised by G. Herranz, defense expected for 2025
  3. Ondrej Novak, Supervised by G. Herranz/M. Veis (Charles Univ. Prague), defense expected for 2025
  4. Fereshteh Masoudinia, Supervised by G. Herranz and Gyanendra Singh, defense expected for 2026

POSTDOCTORAL TRAINING (since 2017, supervised by. Gervasi Herranz):

2017-20 Dr. Mikko Kataja (coming from Aalto University, Finland). Postdoctoral contract (2017-18) and Marie-Sklodowska Fellow (2018-20). Current postion: Optical Engineer / OptoFidelity Oy (company in Finland). Supervisor: Gervasi Herranz

2021-  Dr. Gyanendra Singh (coming from ESPCI-Paris Tech and Chalmers University, Sweden). Beatriu de Pinós Fellow. Supervisor: Gervasi Herranz

2023- Dr. Janine Gückelhorn (coming from Walther-Meissner-Institute, Germany). Postdoc Fellow financed by the project Heavy Element-Free Green Electronics (HEGEL), Reference:  TED2021-129857B-I00. Supervisor: Gervasi Herranz

BACHELOR THESES (since 2017):

  1. Llorenç Benaches Magraner, UABDegree on Physics. Supervisor: G. Herranz January 2023
  2. Ariadna Soro Álvarez. UAB. Mathematics & Physics. Sup.: M. Kataja/ G. Herranz June 2018
  3. Jordi Rubio Serrano. UAB. Degree on Physics. Supervisor: G. Herranz; July 2019
  4. Òscar Díaz Duran. UAB. Degree on Physics. Supervisor: G. Herranz; July 2019
  5. Xavier Domingo Soldado. UAB. Degree on Physics. Supervisor: G. Herranz; July 2019
  6. Guillem Müller Rigat. UAB. Degree on Physics. Sup.: M. Kataja/G. Herranz; July 2019
  7. Genís Guillem Mimó. UAB. Degree on Physics&Chemistry. Sup.:/G. Herranz; July 2020

INTERSHIPS, PhD students (since 2017):

  1. Lluís Nocete Pladevall, JAE Intro 2023, from UAB University, April-September 2023
  2. Mathis Desseaux, from University of Montpellier, April-June 2023
  3. Ayan Banerjee, Master in Quantum Science and Technology, University of Barcelona, Jan 2023- June 2023
  4. Quentin Minon, Polytech. Nantes (France), June-July 2022 
  5. Anna Fritschen. TU Darmstadt, Germany, Supervisor: G. Herranz; January-April 2017
  6. Ondrej Nowak. Charles Univrsity in Prague, Czech Republic Supervisor: G. Herranz, September 2019

G. HERRANZ

Title of the Project: Symmetry and Low-Dimensionality Mine-and-Craft for Efficient Spin Manipulation and Photoconversion (SymDim)
Reference:  PID2020-118479RB-I00
Principal Investigators: G. Herranz, J. Gazquez
Funding Agency: Ministerio de Economía, Industria y Competitividad
Period: 01/09/2021-31/08/2024
Amount: 230 k€

Title of the Project: All-electrical control of spintronic devices
Reference:  Beatriu de Pinós Fellowship 2019 BP 00207
Principal Investigator: G. Herranz
Funding Agency: AGAUR (Generalitat de Catalunya)
Period: 01/04/2021-31/03/2024
Amount: 158 k€

Title of the Project: Spin Generation and Manipulation using 2D Materials and Functional Oxides SPIN2DFUN 
Principal Investigator: G. Herranz
Funding Agency: Ministerio de Economía, Industria y Competitividad through CEX2019-000917-S Severo Ochoa Project
Period: 01/09/2021-31/08/2023
Amount: 70 k€

Title: Heavy Element-Free Green Electronics (HEGEL)
Reference:  TED2021-129857B-I00
Principal Investigators: G. Herranz, J. Herrero
Funding Agency: Ministerio de Economía, Industria y Competitividad
Period: 01/12/2022-30/11/2024
Amount: 264,5 k€

Title of the Project: Suport a Grups de Recerca (SGR 2023-2025): “Multifunctional and Magnetic Materials for Oxide Electronics (MUMOX)”
Reference:  2021 SGR 00445
Principal Investigator: G. Herranz
Funding Agency: AGAUR (Generalitat de Catalunya)
Period: 01/01/2023-31/12/2027
Amount: 60 k€

C. O. AVCI

[1] European Research Council Starting Grant (ERC-StG)
02/2021 – 01/2026
1’916’585 €
MAGNEPIC – Magnetic Insulators: An Enabling Platform for Innovative Spintronic Concepts

[2] Severo Ochoa FUNFUTURE – Frontier Interdisciplinary Projects 2020 Call (ICMAB-CSIC)
09/2021 – 08/2023
70’000 €
SPIN2DFUN – Spin Generation and Manipulation Using 2D Materials and Functional Oxides (joint project with Gervasi Herranz)

[3] PROYECTOS DE GENERACIÓN DE CONOCIMIENTO 2021 (Plan Nacional), Ministerio de Ciencia e Innovación
09/2022 – 08/2025
145’200€ 
MAISKY – MAgnetic Insulator-based SKYrmion spintronics

[4] PROYECTOS DE TRANSICIÓN ECOLÓGICA Y TRANSICIÓN DIGITAL 2021, Ministerio de Ciencia e Innovación
12/2022 – 11/2024
166’750€ 
CONVERT – Converting Waste Heat to Electricity in Microelectronics using Spintronic Thermopower (individual)

[5] M-ERA.NET Joint Call 2022 – Agencia Estatal de Investigación, Proyectos de Colaboración Internacional
10/2023 – 09/2026
195’000€ (total budget 450’000€)
MUST – Materials for Ultraefficient chiral SpinTronics (Coordinator  /  joint project with 2 partners from Poland, 1 partner from Turkey)

J. GAZQUEZ

Competitive calls for large facilities experiments:

Title of the Project: Electron-phonon coupling in SrVO3 thin films
Reference: CNMS2023-A-01814, Principal Investigator: J. Gazquez
Funding Agency: Center for Nanophase Materials Sciences (Oak Ridge National Laboratory, USA)
Period: 01/01/2023-31/12/2023
Granted access to CNMS facilities, in particular to a low-voltage (60-100kV) monochromated, aberration-corrected (MAC)-STEM/EELS (Nion Hermes)

2023

Enhanced spin current transmissivity in Pt/CoFe2O4 bilayers with thermally induced interfacial magnetic modification
M. Gamino, A. B. Oliveira, D. S. Maior, P. R. T. Ribeiro, F. L. A. Machado, T. J. A. Mori, M. A. Correa, F. Bohn, R. L. Rodríguez-Suárez, J. Fontcuberta, and S. M. Rezende.
Phys. Rev. B. 2023 108, 224402

High-Temperature Synthesis of Ferromagnetic Eu3Ta3(O,N)9 with a Triple Perovskite Structure
Jhonatan R. Guarín, Carlos Frontera, Judith Oró-Solé, Jaume Gàzquez, Clemens Ritter, Josep Fontcuberta*, and Amparo Fuertes.
Inorg. Chem. 2023, 62, 42, 17362–17370

Band Alignment and Photoresponse of LaFeO3-Based Heterojunctions
Yunwei Sheng, Mathieu Mirjolet, Mario Villa, Jaume Gàzquez, José Santiso, Andreas Klein, Jordi Fraxedas, and Josep Fontcuberta.
Phys. Rev. Applied 19, 024001 (2023)

Sputtered terbium iron garnet films with perpendicular magnetic anisotropy for spintronic applications
S. Damerio, and C. O. Avci,
J. Appl. Phys. 133, 073902 (2023)

Leveraging symmetry for an accurate spin-orbit torques characterization in ferrimagnetic insulators
M. Testa-Anta, C.-H. Lambert, and C. O. Avci, 
Adv. Electron. Mater. (2023) in press

A transversal approach to predict surface charge compensation in piezoelectric force microscopy
Huan Tan, Jike Lyu, Yunwei Sheng, Pamela Machado, Tingfeng Song, Akash Bhatnagar, Mariona Coll, Florencio Sánchez, Josep Fontcuberta, Ignasi Fina  
Applied Surface Science, 607, 154991, 2023

Untwining polar contributions from light-polarization dependent photovoltaic response of LuMnO3-based ferroelectric capacitors
Yunwei Sheng, Huan Tan, Alberto Quintana, Mario Villa, Jaume Gázquez, Ignasi Fina, Josep Fontcuberta
Acta Materialia, 245, 118601, 2023

Ferroelectric Electroresistance after a Breakdown in Epitaxial Hf0.5Zr0.5O2 Tunnel Junctions
Xiao Long, Huan Tan, Florencio Sánchez, Ignasi Fina*, and Josep Fontcuberta
ACS Appl. Electron. Mater. 2023, 5, 2, 740–747 (2023)

Interface physics in complex oxide heterostructures

RESEARCH AREAS

Interface physics in complex oxide heterostructures

Transition metal oxides are considered to be the perfect candidate for the development of cheap, compact, green and energy-efficient devices because they are earth-abundant and can host a vast amount of electrical, magnetic, and optical properties. The structural quality of oxide heterostructures now rivals that of the best conventional semiconductors, allowing to envisage an oxide electronics era. However, for implementing such functional material systems in technological applications, it is necessary to understand how to control and engineer their properties at the nanoscale. In MULFOX, we investigate the evolution of these properties when two or more complex oxides are brought together. Various effects can take place including the change of lattice distortions (epitaxial strain), electrostatic coupling when materials with different polarity are involved (polar catastrophe), charge transfer via chemical potential shift, frustration due to sublattice connectivity (oxygen octahedra and tetrahedra), size effects due to reduced dimensionality, structure-periodicity tuning (superlattices) and so on. The idea is to explore the phase diagrams of complex oxide heterostructures to assemble the knowledge required for developing the technologies of tomorrow.

Researchers

  • Gabriele De Luca

Continue reading

Gabriele De Luca

Dr. Gabriele De Luca is a Ramón y Cajal researcher at the Institute of Materials Science of Barcelona (ICMAB-CSIC) since January 2023. He performed his undergraduate studies in Physics in Napoli and received his Ph.D. degree in Materials Science from ETH Zürich in 2017. Later, he has been a postdoctoral researcher at the University of Zürich between 2018-2021 and a visiting researcher in University of Wisconsin-Madison in 2019. He was then awarded a SNF Postdoc.Mobility grant (Swiss equivalent to MSCA) to work in the Catalan Institute of Nanoscience and Nanotechnology (ICN2) between 2021-2022. His research focuses on the growth and characterization of complex oxide heterostructures and the evolution of their functional properties at the nanoscale.

Research Area

  • Transition metal oxides are considered to be the perfect candidate for the development of cheap, compact, green and energy-efficient devices because they are earth-abundant and can host a vast amount of electrical, magnetic, and optical properties. The structural quality of oxide heterostructures now rivals that of the best conventional semiconductors, allowing to envisage an oxide electronics era. However, for implementing such functional material systems in technological applications, it is necessary to understand how to control and engineer their properties at the nanoscale.
  • In MULFOX, we investigate the evolution of these properties when two or more complex oxides are brought together. Various effects can take place including the change of lattice distortions (epitaxial strain), electrostatic coupling when materials with different polarity are involved (polar catastrophe), charge transfer via chemical potential shift, frustration due to sublattice connectivity (oxygen octahedra and tetrahedra), size effects due to reduced dimensionality, structure-periodicity tuning (superlattices) and so on. The idea is to explore the phase diagrams of complex oxide heterostructures to assemble the knowledge required for developing the technologies of tomorrow.

Congratulations Dr. Xiao Long, new ICMAB PhD Graduate!

Doctor Xiao Long the Multifunctional Thin Films and Complex Structures (MULFOX) group at ICMAB-CSIC, defended his PhD thesis “Photoresistance and electroresistance in ferroelectric tunnel junctions based on BaTiO3 and Hf0.5Zr0.5O2” on Friday, 25 November 2022 at ICMAB. 

The PhD thesis was supervised by Josep Fontcuberta and Ignasi Fina from the Multifunctional Thin Films and Complex Structures (MULFOX) group at ICMAB-CSIC. The PhD Committee that evaluated the Thesis was formed by Jordi Sort Viñas, Universitat Autònoma de Barcelona (President), Javier Tornos, Universidad Complutense de Madrid (Secretary) and Monica Burriel, Université Grenoble Alpes, France (Vocal).

Doctor Xiao Long’s PhD thesis was part of the PhD Programme in Materials Science from the Universitat Autònoma de Barcelona (UAB).

Ondrej Novak

Mr. Ondrej Novak graduated in Physics at the Charles University in Prague, Czech Republic. He has a Master degree in Optics and Optoelectronics. He joined the lab in September 2022 to start his PhD Thesis on “Topological phase transitions in photonic crystals” under supervision of Dr. Gervasi Herranz as a part of a co-tutelled Thesis with Prof. Martin Veis (Charles University in Prague)

 

Talk at the International Workshop on Oxide Electronics (WOE28)

Gervasi Herranz delivers a talk at the International Workshop on Oxide Electronics (https://iwoe28.events.yale.edu/), Portland, Maine, USA: The talk is entitled “Light-matter interactions modulated by electron-lattice coupling in transition metal oxides” and is held on Wednesday 5 October 2022 (1oh15am).
 

2022

INVITED TALKS

Chiral interlayer coupling in magnetic multilayers
Can Onur Avci
12th International Conference on Magnetic and Superconducting Materials (MSM22)
Aug. 28 – Sep. 02, 2022, Duisburg, Germany

Electrical control of magnetization in magnetic insulators
Can Onur Avci
20th International Symposium on the Physics of Semiconductors and Applications (ISPSA 2022)
Jul. 17-21, 2022, Jeju, Korea

Current-induced magnetization control and chiral interlayer coupling in magnetic heterostructures
Can Onur Avci
24th International Colloquium on Magnetic Films and Surfaces (ICMFS 2022)
Jul 10-15, 2022, Okinawa, Japan

Chiral interlayer coupling in magnetic multilayers
Can Onur Avci
16th International Conference on Nanostructured Materials (Nano2022)
Jun. 6-10, 2022, Sevilla, Spain

Nonlocal detection of out-of-plane magnetization in a magnetic insulator by thermal spin drag
Can Onur Avci
APS March Meeting 2022
Mar. 14-18, 2022, Chicago, USA

Electron-phonon and spin-orbit couplings in early-transition metal in conducting oxides
J. Fontcuberta
SPIN 2022
Bariloche, Argentina, 6th November – 11th November

REGULAR TALKS

Chiral coupling between magnetic layers with orthogonal magnetization
Can Onur Avci
JEMS2022 Joint European Magnetic Symposia
Jul. 24-29, 2022, Warsaw, Poland.

Direct exchange-interactions boost magnetic frustration and a large zero-point entropy in the novel MnTa2N4 diamond-lattice spinel
J. Fontcuberta
Magnetism and Magnetic Materials Conferences MMM 2022 (MInnesota , USA)
Minnesota , USA, 31  october – 4th November

Light-matter interactions modulated by electron-lattice coupling in transition metal oxides
G. Herranz
International Workshop on Oxide Electronics (MInnesota , USA)
Portland, Maine, USA, 5 October 2022

Congratulations Dr. Yunwei Sheng, new PhD graduate!

Doctor Yunwei Sheng from the Multifunctional Thin Films and Complex Structures (MULFOX) Group at ICMAB-CSIC, defended her PhD thesis titled “Photoresponsive polar LuMnO3 and nonpolar LaFeO3 oxides in non-centrosymmetric structures” on Thursday, 27 October 2022 at ICMAB

The PhD thesis was supervised by Josep Fontcuberta and Ignasi Fina, from the Multifunctional Thin Films and Complex Structures (MULFOX) Group at ICMAB-CSIC.

The PhD Committee that evaluated the Thesis was formed by Sylvia Matzen, Paris-Saclay University, France, (President), Mariona Coll Bau, Institut de Ciència de Materials de Barcelona, ICMAB-CSIC (Secretary) and Akash Bhatnagar, Schott AG, Germany (Vocal).

Doctor Yunwei Sheng’s PhD thesis was part of the PhD Programme in Materials Science from the Universitat Autònoma de Barcelona (UAB).

Kyle Shen

Dr. Kyle Shen, director of Laboratory of Atomic & Solid State Physics, Cornell University, spent a Sabbatical Stay in MULFOX-ICMAB for a year (2022.2023). Prof. Shen investigates many-body interactions in quantum materials, with the aim of controlling potentially exotic properties such as superconductivity, magnetism, metal-insulator transitions, and topological properties. Prof. Shen is widely recognized by his expertise in angle-resolved photoemission spectroscopy (ARPES), and synchrotron-based x-ray probes including x-ray absorption spectroscopy and resonant x-ray scattering. A major research thrust is the synthesis and investigation of artificially engineered heterostructures of quantum materials synthesized by molecular beam epitaxy (MBE) with strong electron correlations which allow new emergent states to be created at the interface.

Dr. Kyle Shen at MULFOX

Dr. Kyle Shen, director of Laboratory of Atomic & Solid State Physics, Cornell University, arrives to MULFOX-ICMAB for a Sabatical stay of 12 months.

Congratulations Dr. Tingfeng Song, new graduate!

Doctor Tingfeng Song, from the Multifunctional Thin Films and Complex Structures (MULFOX) Group at ICMAB-CSIC, defended his PhD thesis titled “Doping and interface effects on the ferroelectric properties of epitaxial HfO2-based thin films” on Monday, 19 September 2022 at ICMAB.

The PhD thesis was supervised by Florencio Sánchez and Ignasi Fina, from the Multifunctional Thin Films and Complex Structures (MULFOX) Group at ICMAB-CSIC. 

The PhD Committee that evaluated the Thesis was formed by José Francisco Rivadulla Fernández, Universidad Santiago de Compostela (President), Eric Langenberg Pérez, Universitat de Barcelona (Secretary) and Uwe Schroeder, Namlab, Germany (Vocal).

Doctor Tingfeng Song’s PhD thesis was part of the PhD Programme in Materials Science from the Universitat Autònoma de Barcelona (UAB).

 
 

2022

Bulk photovoltaic effect modulated by ferroelectric polarization back-switching
Yunwei Sheng, Ignasi Fina1, Marin Gospodinov, and  Josep Fontcuberta
Appl. Phys. Lett. 120, 242901 (2022)

Disentangling electronic and thermal contributions to light-induced resistance switching in BaTiO3 ferroelectric tunnel junctions
Xiao Long,  Huan Tan,  Florencio Sánchez,  Ignasi Fina, and  Josep Fontcubertaa)
Journal of Applied Physics 132, 214103 (2022)

Electrical characterization and extraction of activation energies of the defect states in the LaAlO3/SrTiO3 heterostructure featured
Lechaux, Y. Chen, A. Minj, F. Sánchez, G. Herranz, L. Méchin, and B. Guillet
Appl. Phys. Lett. 121, 081904 (2022);  DOI:https://aip.scitation.org/doi/10.1063/5.0101255

MnTa2N4: A Ternary Nitride Spinel with a Strong Magnetic Frustration
Rafael Trócoli, Carlos Frontera, Judith Oró-Solé, Clemens Ritter, Pere Alemany, Enric Canadell, M. Rosa Palacín, Josep Fontcuberta, and Amparo Fuertes
Chem. Mater. 2022, 34, 13, 6098–6107 (2022);  DOI:doi.org/10.1021/acs.chemmater.2c01240

Dynamic control of octahedral rotation in perovskites by defect engineering
Jiahui Jia, Xu He, Arsalan Akhtar, Gervasi Herranz, and Miguel Pruneda
Phys. Rev. B 105, 224112 (2022);  DOI:doi.org/10.1103/PhysRevB.105.224112

Bulk photovoltaic effect modulated by ferroelectric polarization back-switching
Yunwei Sheng, Ignasi Fina, Marin Gospodinov, and Josep Fontcuberta
Appl. Phys. Lett. 120, 242901 (2022);  DOI:doi.org/10.1063/5.0094837

Voltage-driven strain-mediated modulation of exchange bias in Ir20Mn80/Fe80Ga20/Ta/⟨011⟩-oriented PMN-32PT heterostructures
Demirci, J. de Rojas, A. Quintana, I. Fina, E. Menéndez, and J. Sort
Appl. Phys. Lett. 121, 081904 (2022);  DOI:doi.org/10.1063/5.0091231

Two-gap s±-wave superconductivity at an oxide interface
Singh, G. Venditti, G. Saiz, G. Herranz, F. Sánchez, A. Jouan, C. Feuillet-Palma, J. Lesueur, M. Grilli, S. Caprara, and N. Bergeal
Phys. Rev. B 105, 064512 (2022);  DOI:doi.org/10.1103/PhysRevB.105.064512

Enhanced electroresistance endurance of capped Hf0.5Zr0.5O2 ultrathin epitaxial tunnel barriers
Xiao Long, Huan Tan, Saúl Estandía, Jaume Gazquez, Florencio Sánchez, Ignasi Fina and Josep Fontcuberta
APL Materials 10, 031114 (2022);  DOI:doi.org/10.1063/5.0076865

Impact of non-ferroelectric phases on switching dynamics in epitaxial ferroelectric Hf0.5Zr0.5O2 films
Tingfeng Song, Florencio Sánchez, and Ignasi Fina
APL Materials 10, 031108 (2022);  DOI:doi.org/10.1063/5.0083661

Improved polarization and endurance in ferroelectric Hf0.5Zr0.5O2 films on SrTiO3(110)
Tingfeng Song, Huan Tan, Saúl Estandía, Jaume Gàzquez, Martí Gich, Nico Dix, Ignasi Fina and Florencio Sánchez
Nanoscale, 2022,14, 2337-2343 (2022);  DOI:10.1039/D1NR06983G

Efficient spin pumping into metallic SrVO3 epitaxial films
F. Macià, M. Mirjolet , J. Fontcuberta
Journal of Magnetism and Magnetic Materials, 546, 1688711 (2022)

MnTa2N4: A Ternary Nitride Spinel with a Strong Magnetic Frustration

Rafael Trócoli, Carlos Frontera, Judith Oró-Solé, Clemens Ritter, Pere Alemany, Enric Canadell, M. Rosa Palacín, Josep Fontcuberta, and Amparo Fuertes

Chem. Mater. 2022, 34, 13, 6098–6107 (2022);  DOI:doi.org/10.1021/acs.chemmater.2c01240

Magnetic frustration results from competing magnetic interactions and leads to unusual ground states, ranging from non-collinear magnetic orders to spin liquids (SLs), opening the path to new physics and emerging properties. We report the engineered magnetic interaction design and synthesis of the new ternary nitride MnTa2N4 with a normal spinel structure, where the magnetic cations Mn2+ occupy exclusively the tetrahedral sites forming a diamond lattice.
Although the magnetic interactions are strongly antiferromagnetic (θCW ≈ −140 K), a long-range magnetic order is not established, but a smooth magnetic anomaly is observed at T* ≈ 5.1 K, fingerprinting a large magnetic frustration. A short-range helicoidal magnetic order emerges at low temperatures. The ordered moment is ≈70% of the expected magnetic moment of Mn2+ ions and a large part (≈28%) of the spin entropy remains at 400 mK, signaling the coexistence of a helicoidal order with spin-glass-like or SL textures. First-principles calculations unveil an unexpected large direct Mn–Mn exchange interaction that balances the superexchange and accounts for the magnetic frustration. These findings open new avenues toward the design of quantum materials.
 

Dynamic control of octahedral rotation in perovskites by defect engineering

Jiahui Jia, Xu He, Arsalan Akhtar, Gervasi Herranz, and Miguel Pruneda

Phys. Rev. B 105, 224112 (2022);  DOI:doi.org/10.1103/PhysRevB.105.224112

Engineering oxygen octahedra rotation patterns in ABO3 perovskites is a powerful route to design functional materials. Here we propose a strategy that exploits point defects that create local electric dipoles and couple to the oxygen sublattice, enabling direct actuation on the rotational degrees of freedom. This approach, which relies on substituting an A site with a smaller ion, paves a way to couple dynamically octahedra rotations to external electric fields.
A common antisite defect, AlLa, in rhombohedral LaAlO3 is taken as a prototype to validate the idea, with atomistic density functional theory calculations supported with an effective lattice model to simulate the dynamics of switching of the local rotational degrees of freedom to long distances. Our simulations provide an insight of the main parameters that govern the operation of the proposed mechanism, and allow to define guidelines for screening other systems where this approach could be used for tuning the properties of the host material.
 

Bulk photovoltaic effect modulated by ferroelectric polarization back-switching

Yunwei Sheng, Ignasi Fina, Marin Gospodinov, and Josep Fontcuberta

Appl. Phys. Lett. 120, 242901 (2022);  DOI:doi.org/10.1063/5.0094837

Short-circuit photocurrent due to bulk photovoltaic effect displays an oscillatory dependence on the polarization state of light. Here, we explore how the ferroelectric polarization direction in h-LuMnO3 crystals affects the oscillating short-circuit photocurrent. It is shown that after prepoling the crystal at saturation, at remanence, the direction and amplitude of photocurrent oscillations are no longer dictated by prepoling voltage but are largely modulated by polarization back-switching, here ruled by the imprint field.
Thus, the light polarization dependence of photocurrent is also ruled by the imprint field. The impact of these effects on the determination of the Glass coefficients of the material is discussed.
 

Leo Salgado Chane-Pane

Leo Salgado Chane-Pane joined ICMAB-CSIC and the MAGNEPIC project in November 2021. He studied Chemistry at the University of Santiago (Spain), where he obtained his BSc. in 2020. He is currently an MSc. student at the Autonomous University of Barcelona, specializing in Advanced Nanoscience and Nanotechnology. Leo is carrying out his thesis project on current-controlled ferroelectric devices for next-generation nonvolatile data storage.


Email: lsalgado@icmab.es

Teodor Parella Dilmé

Teodor Parella Dilmé joined ICMAB-CSIC and the MAGNEPIC project as a JAE Intro fellow in October 2021. He is a double degree B.Sc. student in physics and chemistry at the Autonomous University of Barcelona. Teo is currently undertaking his bachelor thesis in physics and his research focuses on ionic control of spin-orbit torques in ferrimagnetic insulators.


Email: tparella@icmab.es

Martín Testa Anta

Martín Testa Anta joined ICMAB-CSIC and the MAGNEPIC project as a PhD student in March 2021. He obtained his BSc(Hons) (2015) and MSc (2016) in Chemistry from the University of Vigo (Spain). He subsequently joined the Applied Physics Department at the same university as a predoctoral fellow, where he worked on the synthesis and characterization of magnetic nanocrystals, with particular emphasis on the phenomena that take place at the surface and interfaces between transition metal oxides. His current research is focused on the spin-torque control of magnetization in ferrimagnetic insulators. 


Email: mtesta@icmab.es

Stefano Fedel

Stefano Fedel joined ICMAB-CSIC and the MAGNEPIC project as a PhD student in September 2021. He studied Engineering Physics at Politecnico di Milano (Italy), where he obtained his BCs in 2018 and MSc in 2021. He spent one year as an exchange student at Chalmers University of Technology (Sweden) between 2019 and 2020. Afterward, he carried out his master thesis at ETH Zurich (Switzerland), where he focused on the characterization of spin-orbit torques at the interface between topological insulators and ferromagnet. Stefano’s project deals with the current-driven dynamics of magnetization in magnetic insulators detected by MOKE microscopy.


Email: sfedel@icmab.es

Silvia Damerio

Silvia Damerio joined ICMAB-CSIC and the MAGNEPIC project as a Post-doc researcher in February 2022. She obtained her BSc(Hons) (2015) and MSc(Hons) (2017) in Chemistry from the University of Genova (Italy) and University of Groningen (the Netherlands), respectively. She subsequently joined the Zernike Institute for Advanced Materials of the University of Groningen for her PhD, which she received in 2022 with a thesis about modulated phases in ferroic oxides. Her current research focuses on the study of the spin-flop transition in thin films of ferrimagnetic insulators grown by sputtering.


Email: sdamerio@icmab.es

Spintronic Materials and Devices

RESEARCH AREAS

Spintronic Materials and Devices

Spintronics is a broad and interdisciplinary research field at the intersection of physics, materials science, and nanotechnology. It aims to utilize charge carriers’ intrinsic property “spin” as an active variable in electronic circuits and to offer innovative solutions to future Information Technologies.

In MULFOX, we investigate a wide variety of spintronic-related physical phenomena and materials. On the materials side, our recent efforts focus on thin-film metallic (CoTb, FeTb) and insulating (YIG, TmIG, TbIG, etc.) ferrimagnetic heterostructures with perpendicular magnetic anisotropy. On the physics side, we are interested in spin-orbit torques, spin-charge interconversion, chiral spin textures (domain walls, skyrmions) with the main goal of developing spintronic memory and logic devices with enhanced functionality and high efficiency. Our materials are developed in-house by pulsed laser deposition and magnetron sputtering tools. We then fabricate devices and characterize them using our state-of-the-art electrical and optical probe stations performing harmonic Hall effect, magnetoresistance, Magneto-optic Kerr effect microscopy measurements, etc.

Researchers

C. Avci

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Atomic scale mappig of materials

RESEARCH AREAS

Atomic scale mappig of materials

The role of reduced dimensionality and the structure of interfaces, point and planar defects, dislocations, etc, remains obscure in many cases but are central to macroscopic materials properties. Imaging interfaces and defects at sub-Angstrom resolution, and chemical mapping at atomic level are some of the hot points to be addressed in materials science.

We concentrate on establishing relations between the structure, chemistry and physical properties of transition-metal oxide nanostructures by means of scanning transmission electron microscopy (STEM) and electron energy-loss spectroscopy (EELS). The recent successful correction of aberrations in electron optics allows us accessing the structure and chemistry of low dimensional materials due to its unparalleled spatial resolution, and combined with monochromated EELS it has the potential to probe optical excitations—plasmons, photons, excitons— with sub-nanometer resolution. This gives unprecedented power to understand the ultimate origin of the properties of materials at the nanoscale.

Researchers

Jaume Gàzquez

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Voltage-driven strain-mediated modulation of exchange bias in Ir20Mn80/Fe80Ga20/Ta/⟨011⟩-oriented PMN-32PT heterostructures

E. Demirci, J. de Rojas, A. Quintana, I. Fina, E. Menéndez, and J. Sort

Appl. Phys. Lett. 121, 081904 (2022);  DOI:doi.org/10.1063/5.0091231

Manipulation of exchange bias with electric field is appealing to boost energy efficiency in spintronic devices. Here, this effect is shown at room temperature in Ir20Mn80/Fe80Ga20/Ta layers grown onto ⟨011⟩-oriented PMN-32PT single crystals. After magnetic field-cooling (FC) along the [01-1] and [100] in-plane directions of PMN-32PT and upon allowing the system to relax through consecutive hysteresis loops (training effect), the exchange bias field (HEB) is measured under the action of voltage (out-of-plane poling). Depending on the applied voltage (magnitude and sign), HEB can either increase or decrease with respect to its value at 0 V. The relative variations of HEB are 24% and 5.5% after FC along the [01-1] and [100] directions, respectively.

These results stem from strain-mediated magnetoelectric coupling. The applied electric field causes changes in the coercivity and the squareness ratio of the films, suggesting a reorientation of the effective magnetic easy axis in Fe80Ga20. However, larger HEB values are observed when the squareness ratio is lower. It is claimed that the effect of voltage is equivalent to an in-plane component of an applied magnetic field oriented perpendicular to the cooling field direction. Perpendicular in-plane magnetic fields have been shown to induce an increase in exchange bias in some ferromagnetic/antiferromagnetic systems due to partial recovery of the untrained antiferromagnetic state. Remarkably, here, this effect is directly induced with voltage, therefore enhancing energy efficiency.

 

Orders and dynamics in oxides

RESEARCH AREAS

Orders and dynamics in oxides

Solids may display a variety of order parameters, such as magnetic, polar, charge, orbital, etc. that determine complex phase diagrams where different properties are at display. Exciting prospects emerge towards new understanding that goes deep into the nature of condensed matter and its responsiveness and open perspectives of novel applications. 

Building on a long and wide expertise on transition metal oxides, our current research spans several branches. First, charge dynamics in transition metals oxides as a tool to explore charge-lattice coupling. Next, light-matter interaction in polar materials and heterostructures which offer new opportunities for above-band gap photoresponsive materials and sensing. Last, spin-orbit interactions in solids is emerging as new tool towards energy efficient spintronic devices. Whereas spin-orbit coupling in heavy metals is known and much used, plenty of room is still available for light transition metals, which are cheaper and more abundant, and were spin dynamics may offer new opportunities. 

Researchers

J. Fontcuberta

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Two-gap s±-wave superconductivity at an oxide interface

G. Singh, G. Venditti, G. Saiz, G. Herranz, F. Sánchez, A. Jouan, C. Feuillet-Palma, J. Lesueur, M. Grilli, S. Caprara, and N. Bergeal

Phys. Rev. B 105, 064512 (2022);  DOI:doi.org/10.1103/PhysRevB.105.064512

After half a century of debate, superconductivity in doped SrTiO3 has come to the fore again with the discovery of interfacial superconductivity in the LaAlO3/SrTiO3 heterostructures. While these interfaces share the interesting properties of bulk SrTiO3 , quantum confinement generates a complex band structure involving bands with different orbital symmetries whose occupancy is tunable by electrostating doping.
Multigap superconductivity has been predicted to emerge in LaAlO3/SrTiO3 at large doping, with a Bose-Einstein condensation character at the Lifshtiz transition. In this article, we report on the measurement of the upper critical magnetic field Hc2 of superconducting (110)-oriented LaAlO3/SrTiO3 heterostructures and evidence a two-gap superconducting regime at high doping. Our results are quantitatively explained by a theoretical model based on the formation of an unconventional s±-wave superconducting state with a repulsive coupling between the two condensates.

Enhanced electroresistance endurance of capped Hf0.5Zr0.5O2 ultrathin epitaxial tunnel barriers

Xiao Long, Huan Tan, Saúl Estandía, Jaume Gazquez, Florencio Sánchez, Ignasi Fina and Josep Fontcuberta

APL Materials 10, 031114 (2022);  DOI:doi.org/10.1063/5.0076865

Electroresistance in ultrathin Hf0.5Zr0.5O2 (HZO) films is pivotal toward the implementation of hafnia-based ferroelectrics in electronics. Here, we show that the electroresistance yield and endurance of large capacitors (∼314 µm2) of epitaxial HZO films only 2.2 nm thick grown on SrTiO3 or GdScO3 can be improved using 1 nm SrTiO3 capping layers. It is argued that the main role of the capping layer is to minimize charge transport along grain boundaries, and, thus, a similar strategy can be explored in polycrystalline films
Electroresistance in ultrathin Hf0.5Zr0.5O2 (HZO) films is pivotal toward the implementation of hafnia-based ferroelectrics in electronics. Here, we show that the electroresistance yield and endurance of large capacitors (∼314 µm2) of epitaxial HZO films only 2.2 nm thick grown on SrTiO3 or GdScO3 can be improved using 1 nm SrTiO3 capping layers. It is argued that the main role of the capping layer is to minimize charge transport along grain boundaries, and, thus, a similar strategy can be explored in polycrystalline films
 

Impact of non-ferroelectric phases on switching dynamics in epitaxial ferroelectric Hf0.5Zr0.5O2 films

Tingfeng Song, Florencio Sánchez, and Ignasi Fina

APL Materials 10, 031108 (2022);  DOI:doi.org/10.1063/5.0083661

Determining the switching speed and mechanisms in ferroelectric HfO2 is essential for applications. Switching dynamics in orthorhombic epitaxial ferroelectric Hf0.5Zr0.5O2 films with either significant or negligible presence of monoclinic paraelectric phase is characterized.
Switching spectroscopy reveals that the polarization dynamics in pure orthorhombic ferroelectric phase films can be modeled by the Kolmogorov–Avrami–Ishibashi mechanism with large characteristic time (≈1 µs), which is shortened in fatigued junctions. The long switching time indicates that non-archetypical switching mechanisms occur and that ionic motion or other extrinsic contributions might be at play. Films containing a higher amount of paraelectric monoclinic phase show a shorter switching time of 69 ns, even in pristine state, for applied electric field parallel to the imprint field, enabling synaptic-like activity using fast electric stimuli. Thus, the presence of defects or paraelectric phase is found to improve the switching speed, contrary to what one can expect a priori.
 

Cryogenic radiation and particle detectors with superconductors

RESEARCH AREAS

Cryogenic radiation and particle detectors with superconductors

Our research focuses on the development of superconducting radiation and particle detectors, operating at very low temperatures, for astrophysics, particle physics and quantum technologies. Each application requires development of suitable materials and designs, including absorbers, and the study of the relevant physical phenomena that determine their performances.  

Cryogenic detectors based on superconductors display unprecedented performances. Combining nearly zero dark counts, very low thresholds, excellent sensitivity and high quantum efficiency, they are essential for new instruments in astrophysics and cosmology, and are considered next frontier, strategic instrumentation, with applications in quantum technologies, security, biomedicine, environment and several industries.

Our research concentrates on the so-called Transition-Edge Sensors (TES); making use of a very sharp superconducting transition, they constitute extremely sensitive microcalorimeters and bolometers operating at temperatures far below 1K. We accumulate years of expertise in the development of Mo/Au based TES for X-ray astrophysics. Recently we have extended our interests towards the development of prototypes for (1) detection of lower energy photons, in the NIR-VIS-UV, for applications in photonics and astronomy; and (2) phonon detection for direct search of low-mass dark matter.

Researchers

L. Fábrega

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Quantum transport and light-matter interactions

RESEARCH AREAS

Quantum transport and light-matter interactions

The focus is on electronic transport in bulk crystals and low-dimensional systems, and their interaction with light. We study quantum wells formed at the interface between transition metal oxides, with emphasis on spin-orbit physics and superconductivity. We also study the interaction of electromagnetic waves at optical wavelengths with transition metal systems and photonic crystals. 

We investigate electronic transport in oxide quantum wells in transition metal perovskites (involving, e.g., SrTiO3– and KTaO3- interfaces). Our focus is on Rashba spin-orbit fields and unconventional superconductivity for application in spintronics and quantum technologies. In parallel, we investigate light-matter interactions in different systems. In the area of photonic and plasmonic crystals, our interest is in achieving nonreciprocal propagation of confined electromagnetic waves, tunable with external fields, of interest for integrated photonic circuitry. On the other hand, we investigate the possibility of using electromagnetic waves to entangle spin and orbital degrees of freedom in transition metals. The idea behind is to explore theoretical models and find experimental optical signatures of spin-orbital mixing in strongly correlated systems that could serve as platform to achieve entanglement for quantum technologies.

Researchers

G. Herranz

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Improved polarization and endurance in ferroelectric Hf0.5Zr0.5O2 films on SrTiO3(110)

Tingfeng Song, Huan Tan, Saúl Estandía, Jaume Gàzquez, Martí Gich, Nico Dix, Ignasi Fina and Florencio Sánchez

Nanoscale, 2022,14, 2337-2343 (2022);  DOI:10.1039/D1NR06983G

The metastable orthorhombic phase of Hf0.5Zr0.5O2 (HZO) can be stabilized in thin films on La0.67Sr0.33MnO3 (LSMO) buffered (001)-oriented SrTiO3 (STO) by intriguing epitaxy that results in (111)-HZO oriented growth and robust ferroelectric properties. Here, we show that the orthorhombic phase can also be epitaxially stabilized on LSMO/STO(110), presenting the same out-of-plane (111) orientation but a different distribution of the in-plane crystalline domains.
The remanent polarization of HZO films with a thickness of less than 7 nm on LSMO/STO(110) is 33 μC cm−3, which corresponds to a 50% improvement over equivalent films on LSMO/STO(001). Furthermore, HZO on LSMO/STO(110) presents higher endurance, switchable polarization is still observed up to 4 × 1010 cycles, and retention of more than 10 years. These results demonstrate that tuning the epitaxial growth of ferroelectric HfO2, here using STO(110) substrates, allows the improvement of functional properties of relevance for memory applications.
 

Can Onur Avci

Dr. Can Onur Avci is a principal investigator at the Institute of Materials Science of Barcelona (ICMAB-CSIC) since February 2021. He received his Ph.D. degree from ETH Zürich in 2015 and was awarded the ETH Medal for outstanding doctoral thesis. He has been a postdoctoral researcher at the Massachusetts Institute of Technology between 2016-2018 and at ETH Zürich between 2018 and 2021. He recently received an ERC Starting Grant to develop spintronics devices based on magnetic insulators. His research focuses on spin-orbit-driven phenomena and spin currents in low dimensional systems, electrical control of magnetization, and spintronic memory and logic devices.

Jaume Gázquez

Biography

In 2007 I obtained my PhD in Materials Science at the Universitat Autònoma de Barcelona. Afterwards I joined the STEM Group of the Oak Ridge National Laboratory as a postdoc under the supervision of Dr. Maria Varela and Dr. Steve Pennycook. In September 2010 I joined back the ICMAB as a JAE-doc. In 2013 I could secure a 5-year Ramón y Cajal contract to start independent research at ICMAB. Since July 2020 I am a CSIC Tenured Scientist.

Research interest

My research concentrates on establishing relations between the structure, chemistry and physical properties of transition-metal oxide nanostructures. The role of reduced dimensionality and the structure of interfaces, point defects, dislocations, etc, remains obscure in many cases but are central to macroscopic materials properties. Imaging interfaces and defects at sub-Angstrom resolution, chemical mapping at atomic level are some of the hot points to be addressed in materials science. The richness of an aberration corrected scanning transmission electron microscopy (STEM), in which a very tiny electron probe (of the order of 1 Å) is scanned over the specimen, is to collect several signals in parallel, allowing to combine structural imaging and spectroscopic imaging, electron energy loss spectroscopy (EELS) for example, with atomic resolution.

Gervasi Herranz

Research Leader in Functional Oxide Interfaces and Photonics

The celebrated phrase “the interface is the device” is my favorite motto to describe my research activity, which aims at uncovering new physical phenomena at the boundary of materials, for new concepts and applications.

Until 2008, my focus was on the research on functional oxides, exploiting their magnetic and transport properties. Yet, well before my appointment at ICMAB, my previous scientific experience Ied me to the convincement that exploiting also the optical properties of functional interfaces was an endless source of inspiration for new physics. In 2008, my new permanent position as a tenured researcher at ICMAB-CSIC gave me the opportunity to bring these new ideas and concepts into life.

This background has brought to my major achievements in the fields of oxide functional interfaces and photonics. My most notorious highlights in the last four years include: (i) The possibility of manipulating the electronic structure of oxide quantum wells to realize tailored properties for applications, mainly in electronics (Physical Review Letters 109, 226601 (2012), Scientific Reports 2, 758 (2012), Physical Review Letters 113, 156802 (2014), Nature Communications 6, 6028 (2015), ii) the tuning of electronic orbital polarization at oxide surfaces (Nature Communications 3, 1189 (2012)); the tailoring of the magneto-optic activity exploiting photonic-band effects (ACS Nano, 5, 2957(2011), Nanoscale 3, 4811 (2011)) and (iv) exploiting plasmons for enhanced magnetooptics (Langmuir, 28, 9010 (2012), Physical Review Applied 2, 054003 (2014).

I have supervised three Master Theses and three PhD Theses (two more are in progress). My results have been published in 71 articles (during the last six years I have published 12 articles in journals with index of impact higher than 5) and my h-index is h = 20. I have been awarded with 12 invited lectures in international conferences during the last 6 years (among them, APS March Meeting (twice), MRS Spring, SPIE, CIMTEC and Intermag conferences). I have co-authored a book chapter in the field of photonics (2013). My scientific record is available at http://www.researcherid.com/rid/G-2770-2014.

One of my endeavors has been to be in contact with the scientific community and boost the communication and knowledge exchange. With this in spirit, I have been organizer in two MRS Spring symposia (one as lead coordinator) and I am also leading the organization of one symposium in EMRS 2015 in functional oxides. At the same time, I have been invited as lecturer in different Schools worldwide to lecture on oxide physics and photonics.   

Lourdes Fàbrega

Cryogenic radiation detectors, working at temperatures well below 1K, are considered the next generation of instrumentation for a wide variety of applications. Among them, superconducting Transition Edge Sensors (TESs) are nowadays at the frontline. TESs are ultrasensitive microcalorimeters or bolometers useful for a very wide radiation range, from gamma-rays to microwaves and particles. Although initially developed mainly for astronomic instruments, either on ground or in space, their performances, the maturity achieved and the progress on cryogenics have open many other niches for them, in applications such as industry, materials science and quantum information. In particular, TESs have already been installed in electron microscopes and in several synchrotron lines.

My research focuses in the development (design, fabrication and characterization) of X-ray detectors based on Mo/Au-based TES, for Space and other applications, such as dark matter search or materials science. I’m also interested in the physics of these devices: indeed, in spite of the extraordinary development of TES and their achieved performances, there is still room for them to further approach the theoretically predicted limits. Specific work to this end involves understanding the nature of the superconducting transition, and electrothermal modeling to determine and reduce the so-called unexplained noise.

Josep Fontcuberta

I’m mostly interested on functional oxides. These strongly correlated electronic systems display fascinating ferroic (i.e. magnetic, ferroelectric), electric and optical properties, that have motivated my research and that of the group I’ve led. I’m a material’s scientist and I have devoted much effort to the preparation and growth of epitaxies of complex oxides and to the study of the relationship between their structure, microstructure and functional properties. Nowadays, my research activity is focused on exploiting oxide thin films for efficient data storage using magnetic and ferroelectric materials, and their potential use in photovoltaics for energy harvesting and as transparent metallic electrodes. I’m persuaded that oxides can play a very important role in advanced high-tech devices and I’m pushing for the development of either new applications or new-concept devices.

Impact of La Concentration on Ferroelectricity of La-Doped HfO2 Epitaxial Thin Films

T. Song, H. Tan, R. Bachelet, G. Saint-Girons, I. Fina,* F. Sánchez*

ACS Appl. Electron. Mater. 2021, 3, 11, 4809–4816;  DOI: doi.org/10.1021/acsaelm.1c00672

 

Epitaxial thin films of HfO2 doped with La have been grown on SrTiO3(001) and Si(001), and the impact of the La concentration on the stabilization of the ferroelectric phase has been determined. Films with 2–5 at. % La doping present the least amount of paraelectric monoclinic and cubic phases and exhibit the highest polarization, having a remanent polarization above 20 μC/cm2. The dopant concentration results in an important effect on the coercive field, which is reduced with increasing La content. Combined high polarization, high retention, and high endurance of at least 1010 cycles is obtained in 5 at. % La-doped films.

2020

Optically Controlled Ferroelectric Memristors (OPTOFEM 2020)
October, 22-23, 2020, in an online format, due to the current COVID-19
OPTOFEM 2020 

2018

COST TO-BE Spring Meeting 2018
Organized by the Institut de Ciència de Materials de Barcelona and held in the Eden Roc Hotel at Sant Feliu de Guíxols, north of Barcelona
12th–14th March 2018
https://congresses.icmab.es/tobe2018

 

2007

5th Thin Film Oxide Meeting THIOX
European Science Foundation
Sant Feliu de Guixols, 28-30 Mrch 2007
Chair: Josep Fontcuberta

2009

16th International Workshop on Oxide Electronics; 16th WOE
Tarragona, October 2009
Chairs : Josep Fontcuberta
2nd European School on Multiferroics 2008
Girona, Septembre 2008
Chairs: Josep Fontcuberta & Jens Kreisel

2011

E-MRS Fall Meeting 2011
Symposium A: “Stress, structure, and stoichiometry effects on the properties of nanomaterials”
September 19 – 23, 2011
Warsaw University of Technology, Poland
Symposium G: “Complex Oxide Materials for Emerging Energy Technologies”
San Francisco, USA
Chairs: Valentin Craciun (Materials Science and Engineering, University of Florida); Thomas Schroeder (IHP Microelectronics / Materials Research, Frankfurt-Oder)
Rolly Gaboriaud (Institut Pprime – CNRS) Florencio Sánchez (ICMAB-CSIC)
MRS Spring Meeting 2011
Symposium G: “Complex Oxide Materials for Emerging Energy Technologies”
San Francisco, USA
Chairs: Ho Nyung Lee (Oak Ridge National Laboratory); Akira Ohtomo (Tokyo Institute of Technology); Gervasi Herranz (ICMAB-CSIC); John Perkins  (National Renewable Energy Laboratory)

2013

European Materials Reserch Society Fall Meeting – EMRS 2013
Varsaw (Poland), 16-20 September 2013
Symposium B: Stress, structure, and stoichiometry effects on the properties of nanomaterials II
Organizers: F. Sánchez, V. Craciun, D. Kumar and F. Paumier

MRS 2013 Spring Meeting
San Francisco (USA), 1-5 April 2013
Symposium XX: Oxide Thin Films and Heterostructures for Advanced Information and Energy Technologies
Symposium Organizers:
Gervasi Herranz, Institut of Materials Science of Barcelona ICMAB-CSIC
Ho Nyung Lee, Oak Ridge National Laboratory
Jens Kreisel, Luxembourg University,CRP Lippmann – Materials Sciences
Hiromichi Ohta, Nagoya University, Graduate School of Engineering

MAMA-Trend: Trends, challenges and emergent new phenomena in multi-functional material)
Sorrento, April 2013
Symposium 2: Dielectrics, ferroelectrics and multiferroics.
Symposium Organizers: Josep Fontcuberta (ICMAB-CSIC, Bellaterra, Spain); M. Bibes (CNRS-Thales, Palaiseau, France) and S. Picozzi (CNR-SPIN, L’Aquila, Italy)
School on “Pulsed laser deposition and sputtering”
ICMAB, Bellaterra, 24 – 25 Enero de 2013
Organizers: Florencio Sanchez and N. Dix

2015

European Materials Research Society Fall Meeting, Symposium: “Towards oxide-based electronics: growth and applications of oxide thin films and heterostructures, EMRS
Varsovia (Polonia), 15-18 September 2015
Co-organizes: Florencio Sánchez

Materials Research Society Spring Meeting – MRS, Symposium: “Oxide thin films and nanostructures for advanced electrical, optical and magnetic applications”
San Francisco (USA), 06-10 de abril de 2015
Co-organizes: Florencio Sánchez

International Conference on Magnetism  (2015)
Barcelona  July 2015
Program Committee: Josep Fontcuberta

2010

Universitat Autònoma de Barcelona
Master in Materials Science (2008-2012)
Functional Materials
Professor: Josep Fontcuberta

Universitat Autònoma de Barcelona
Master in Nanoscience Science (2008-2012)
Nanomagnetism
Professor: Josep Fontcuberta

European School of Multiferroics 2010
Lectures on: Electric and magnetic control of magnetization and polarization in multiferroic heterostructures and devices
L’Aquila (Italy) 27th September-1 October (2010)
Professor: Josep Fontcuberta

Universidad Internacional Menéndez Pelayo
Course: “Nuevos retos y aplicaciones del magnetismo”
Lectures on: Multiferroic materials: overview and some prospectives
A Coruña, 19-23 Julio 2010
Professor: Josep Fontcuberta

2009

Universitat Autònoma de Barcelona
Master in Materials Science (2008-2012)
Functional Materials
Professor: Josep Fontcuberta

Universitat Autònoma de Barcelona
Master in Nanoscience Science (2008-2012)
Nanomagnetism
Professor: Josep Fontcuberta

2008

Universitat Autònoma de Barcelona
Master in Materials Science (2008-2012)
Functional Materials
Professor: Josep Fontcuberta

Universitat Autònoma de Barcelona
Master in Nanoscience Science (2008-2012)
Nanomagnetism
Professor: Josep Fontcuberta

2013

Universitat Autònoma de Barcelona
Master in Nanoscience and Materials Science (2011-2012-2013)
Functional Materials
Professor: Josep Fontcuberta

School: ESPCI-ParisTech
Lecture on: Life beyond <001>: reshaping 2DEGS at the LaAlO3/SrTiO3 interface by crystal orientation
November 2013 (Paris, France)
Professor: Gervasi Herranz

School: 6th European School on Multiferroics (ESMF6)
Lecture on: Polarized Light for Spectroscopy and Domain Imaging
July 21-26, 2013, Wittenberg, Germany
Professor: Gervasi Herranz

International School on Oxide Electronics 2013
Lecture on: Polarized Light for Spectroscopy and Domain Imaging
September 2-14, 2013, Cargèse. France
Professor: Gervasi Herranz

International School on Oxide Electronics 2013
Lecture on: Electronic Structure of SrTiO3
06th -20th October, 2011, Cargèse. France
Professor: Gervasi Herranz

School: Pulsed laser deposition
Lecture on: Fundamental of Pulsed Laser Deposition
24-01-2013, ICMAB, Bellaterra
Professor: Florencio Sanchez

 

 

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